Tellurium in organic synthesis için kapak resmi
Başlık:
Tellurium in organic synthesis
Dil:
English
ISBN:
9780080453101

9780080474922
Edisyon:
2nd ed.
Yayın Bilgileri:
London : Academic, 2007.
Fiziksel Tanımlama:
1 online resource (xxv, 372 p.) : ill.
Seri:
Best synthetic methods

Best synthetic methods.
Genel Not:
Previous ed.: 1994.
İçerik:
Introduction -- Preparation of the more important inorganic tellurium compounds -- Preparation of the principal classes of organic tellurium compounds -- Tellurium in organic synthesis -- Telluroheterocycles -- Toxicology of organotellurium compounds -- Pharmacology of organotellurium compounds -- Miscellaneous.
Özet:
The increasing number of publications that use tellurium clearly demonstrates the important role of tellurium compounds as unique and powerful tools in a broad range of organic chemical manipulations, often characterized by their selective behavior. Tellurium in Organic Synthesis provides an overview of the principal aspects of organic tellurium chemistry. Many chapters have been enriched and updated in this second edition. New chapters include overviews of toxicology and pharmacology and a review on the preparation and reactivity of several tellurium heterocycles. The first part of the book focuses on the preparation of selected inorganic tellurium compounds and on the main classes of organotellurium compounds. The second part, and main interest of the book, details the use of these inorganic and organic compounds as reagents to perform specific organic manipulations and synthesis. Reactions covered include reduction, formation and reaction of anionic species, deprotection, tellurium cyclizations, formation of alkenes, use of vinyllic tellurides, free radical chemistry, transmetallations, and removal of tellurium. * Overview of inorganic and organic tellurium chemistry * Synthetic applications of tellurium compounds * All topics accompanied by detailed experimental procedures.

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E-Kitap 1300234-1001 QD412 .T4 P48 2007 eb Elsevier E-Kitap Koleksiyonu
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Özet

Özet

The increasing number of publications that use tellurium clearly demonstrates the important role of tellurium compounds as unique and powerful tools in a broad range of organic chemical manipulations, often characterized by their selective behavior.

Tellurium in Organic Synthesis provides an overview of the principal aspects of organic tellurium chemistry. Many chapters have been enriched and updated in this second edition. New chapters include overviews of toxicology and pharmacology and a review on the preparation and reactivity of several tellurium heterocycles.

The first part of the book focuses on the preparation of selected inorganic tellurium compounds and on the main classes of organotellurium compounds. The second part, and main interest of the book, details the use of these inorganic and organic compounds as reagents to perform specific organic manipulations and synthesis. Reactions covered include reduction, formation and reaction of anionic species, deprotection, tellurium cyclizations, formation of alkenes, use of vinyllic tellurides, free radical chemistry, transmetallations, and removal of tellurium.


İçindekiler

Chapter 1 Introduction
Chapter 2 Preparation of the more important inorganic tellurium compounds
Chapter 3 Preparation of the principal classes of organic tellurium compounds
Chapter 4 Tellurium in organic synthesis
Chapter 5 Telluroheterocycles
Chapter 6 Toxicology of organotellurium compounds
Chapter 7 Pharmacology of organotellurium compounds
Chapter 8 Miscellaneous reactions, including use of TeCl4 as a catalyst